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Some actinide complexes of pyridin-, pyrrol-, furan- and thiophen-aldazine Schiff bases
Authors:Mahmoud M Dawod  Fawwaz I Khalili and Afif M Seyam
Institution:

Department of Chemistry, University of Jordan, Amman, Jordan

Abstract:Actinide chloride complexes with pyridinaldazine (PAA), pyrrolaldazine (PyAA-H2), furanaldazine (FAA), and thiophenaldazine (TAA): An(L)Cln·m-H2O, where An = Th, UO2; L = PAA, PyAA-H2, FAA, TAA; n = 2, 4; m = 0, 2, 3, 5 (also, mononuclear with 2L, dinuclear and trinuclear complexes) have been prepared by the reaction of ThCl4, UO2Cl2 or UO2(Ac)2·2H2O with PAA, PyAA-H2, FAA or TAA and characterized by spectral data, electrical conductance, thermal and elemental analysis.
Keywords:
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