First example of a di-cadmium tris-phthalocyanine triple-decker sandwich complex |
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Authors: | Chambrier Isabelle Hughes David L Swarts Jannie C Isare Benjamin Cook Michael J |
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Institution: | Wolfson Materials and Catalysis Centre, School of Chemical Sciences and Pharmacy, University of East Anglia, Norwich, UK. |
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Abstract: | An unprecedented M(II)2Pc3 (M = Cd) triple-decker sandwich complex has been synthesized and characterised by single crystal X-ray crystallography; cyclic voltammetry shows an unusually large range of redox states and EPR spectroscopy indicates that the material exists in at least two redox states, one having spin (1/2). |
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