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First example of a di-cadmium tris-phthalocyanine triple-decker sandwich complex
Authors:Chambrier Isabelle  Hughes David L  Swarts Jannie C  Isare Benjamin  Cook Michael J
Institution:Wolfson Materials and Catalysis Centre, School of Chemical Sciences and Pharmacy, University of East Anglia, Norwich, UK.
Abstract:An unprecedented M(II)2Pc3 (M = Cd) triple-decker sandwich complex has been synthesized and characterised by single crystal X-ray crystallography; cyclic voltammetry shows an unusually large range of redox states and EPR spectroscopy indicates that the material exists in at least two redox states, one having spin (1/2).
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