Alkylation of active methylene compounds with alcohols catalyzed by an iridium complex |
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Authors: | Morita Masao Obora Yasushi Ishii Yasutaka |
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Institution: | Department of Applied Chemistry, Faculty of Engineering, Kansai University, Yamate-cho, Suita, Osaka 564-8680, Japan. |
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Abstract: | Base-free catalytic alpha-alkylation of active methylene compounds with primary alcohols was successfully achieved using an IrCl(cod)](2) complex in the presence of PPh(3) to afford the corresponding saturated alpha-alkylated products in good yields. |
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