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Alkylation of active methylene compounds with alcohols catalyzed by an iridium complex
Authors:Morita Masao  Obora Yasushi  Ishii Yasutaka
Institution:Department of Applied Chemistry, Faculty of Engineering, Kansai University, Yamate-cho, Suita, Osaka 564-8680, Japan.
Abstract:Base-free catalytic alpha-alkylation of active methylene compounds with primary alcohols was successfully achieved using an IrCl(cod)](2) complex in the presence of PPh(3) to afford the corresponding saturated alpha-alkylated products in good yields.
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