Modular synthesis of block copolymers via cycloaddition of terminal azide and alkyne functionalized polymers |
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| Authors: | Opsteen Joost A van Hest Jan C M |
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| Institution: | Organic Chemistry, Institute for Molecules and Materials, Radboud University Nijmegen, Toernooiveld 1, 6525 ED Nijmegen, The Netherlands. |
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| Abstract: | Polymeric building blocks containing terminal azide and alkyne functionalities are prepared via atom transfer radical polymerization (ATRP) and used to modularly synthesize block copolymers via 1,3-dipolar cycloaddition reactions, which are quantitative according to SEC measurements. |
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