Aryl-aryl interactions as directing motifs in the stereodivergent iron-catalyzed hydrosilylation of internal alkynes |
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| Authors: | Belger Christian Plietker Bernd |
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| Institution: | Institut für Organische Chemie, Universit?t Stuttgart, Pfaffenwaldring 55, D-70569 Stuttgart, Germany. |
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| Abstract: | The defined Fe hydride complex FeH(CO)(NO)(Ph(3)P)(2) is highly active as a catalyst for selective hydrosilylation of internal alkynes to vinylsilanes. Depending on the silane employed either E- or Z-selective hydrosilylation products were formed in excellent yields and good to excellent stereoselectivities. |
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