Cyanide-bridged Fe(III)-Co(II) bis double zigzag chains with a slow relaxation of the magnetisation |
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| Authors: | Toma Luminita Marilena Lescouëzec Rodrigue Lloret Francesc Julve Miguel Vaissermann Jacqueline Verdaguer Michel |
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| Institution: | Department de Química Inorgànica/Instituto de Ciencia Molecular, Facultat de Química de la Universitat de València, Avda. Dr. Moliner 50, 46100-Burjassot (València), Spain. |
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| Abstract: | Reaction of Fe(III)(bipy)(CN)4]- with fully solvated M(II) cations M = Co (1) and Mn (2)] produces the isostructural bis double zigzag chains Fe(III)(bipy)(CN)4]2M(II)(H2O)] x MeCN x (1/2)H2O; 1 exhibits intrachain ferromagnetic and interchain antiferromagnetic couplings, slow magnetic relaxation and hysteresis effects. |
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