New insights into the mechanism of activation of atom transfer radical polymerization by Cu(I) complexes |
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| Authors: | De Paoli Patrizia Isse Abdirisak A Bortolamei Nicola Gennaro Armando |
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| Institution: | Department of Chemical Sciences, University of Padova, via Marzolo 1, 35131, Padova, Italy. |
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| Abstract: | The kinetics of activation of RX by a Cu(I) complex has been investigated in MeCN both in the absence and presence of halide ions. The system Cu(I)/L/X(-) (L = Me(6)TREN) is mainly composed of Cu(I)L(+), XCu(I)L and Cu(I)X(2)(-), but only Cu(I)L(+) is found to be an active catalyst reacting with RX. |
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