Application of a chiral metal-organic framework in enantioselective separation |
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| Authors: | Padmanaban Mohan Müller Philipp Lieder Christian Gedrich Kristina Grünker Ronny Bon Volodymyr Senkovska Irena Baumgärtner Sandra Opelt Sabine Paasch Silvia Brunner Eike Glorius Frank Klemm Elias Kaskel Stefan |
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| Institution: | Westf?lische Wilhelms-Universit?t, NRW Graduate School of Chemistry, Organisch-Chemisches Institut, Corrensstr. 40, 48149 Münster, Germany. |
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| Abstract: | A modular approach for the synthesis of highly ordered porous and chiral auxiliary (Evans auxiliary) decorated metal-organic frameworks is developed. Our synthesis strategy, which uses known porous structures as model materials for incorporation of chirality via linker modification, can provide access to a wide range of porous materials suitable for enantioselective separation and catalysis. Chiral analogues of UMCM-1 have been synthesized and investigated for the enantioseparation of chiral compounds in the liquid phase and first promising results are reported. |
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