Modular self-assembled multiporphyrin cages with tunable shape |
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| Authors: | Alessio Enzo Casanova Massimo Zangrando Ennio Iengo Elisabetta |
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| Institution: | Department of Chemical and Pharmaceutical Sciences, University of Trieste, Trieste, Italy. |
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| Abstract: | Three new molecular cages-a trigonal prism (2) and two cubic-shaped boxes of increasing size (3, 4)-featuring as many as 10 porphyrins were obtained in quantitative yields by self-assembly of a single bis-zincporphyrin metallacycle (1) with appropriate polytopic N-linkers: the trigonal planar tpt or the cruciform porphyrins 4'-TPyP and 4'-TPhPyP. |
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