Chiral induction controlled by aggregation of organometallics: trifluoromethylated aminoalcohols for chiral ligands in Et2Zn alkylation of benzaldehyde |
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Authors: | Katagiri Toshimasa Fujiwara Yasuyuki Takahashi Satoshi Ozaki Nobuyuki Uneyama Kenji |
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Institution: | Department of Applied Chemistry, Okayama University, Tsushimanaka 3-1-1, Okayama 700-8530, Japan. tkata@cc.okayama-u.ac.jp |
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Abstract: | Chiral induction in the reaction of Et2Zn with PhCHO by fluorinated chiral amino alcohols was correlated to the extent of aggregation of Et2Zn species, which was estimated by manometric study. |
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