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Chiral induction controlled by aggregation of organometallics: trifluoromethylated aminoalcohols for chiral ligands in Et2Zn alkylation of benzaldehyde
Authors:Katagiri Toshimasa  Fujiwara Yasuyuki  Takahashi Satoshi  Ozaki Nobuyuki  Uneyama Kenji
Institution:Department of Applied Chemistry, Okayama University, Tsushimanaka 3-1-1, Okayama 700-8530, Japan. tkata@cc.okayama-u.ac.jp
Abstract:Chiral induction in the reaction of Et2Zn with PhCHO by fluorinated chiral amino alcohols was correlated to the extent of aggregation of Et2Zn species, which was estimated by manometric study.
Keywords:
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