Electrophilic aromatic nitration using perfluorinated rare earth metal salts in fluorous phase |
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| Authors: | Shi Min Cui Shi-Cong |
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| Institution: | State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Lu, Shanghai 200032, China. mshi@pub.sioc.ac.cn |
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| Abstract: | In this paper, we describe a practical, useful electrophilic aromatic nitration process in fluorous phase by using perfluorodecalin (C10F18, cis- and trans-mixture) as a fluorous solvent and perfluorinated rare earth metal salt Yb(OSO2C8F17)3] as a catalyst for the electrophilic aromatic nitration. |
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