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Hierarchical Integration of Organic Core/Shell Microwires for Advanced Photonics
Authors:Hong-Tao Lin  Ying-Xin Ma  Song Chen  Prof Xue-Dong Wang
Institution:1. School of Chemistry and Chemical Engineering, Shandong University of Technology, Zibo, Shandong 255000 P. R. China

These authors contributed equally to this work.;2. Institute of Functional Nano & Soft Materials (FUNSOM), Jiangsu Key Laboratory for Carbon-Based Functional Materials & Devices, Soochow University, Suzhou, Jiangsu 215123 China

Abstract:The combination of multiple components or structures into integrated micro/nanostructures for practical application has been pursued for many years. Herein, a series of hierarchical organic microwires with branch, core/shell (C/S), and branch C/S structures are successfully constructed based on organic charge transfer (CT) cocrystals with structural similarity and physicochemical tunability. By regulating the intermolecular CT interaction, single microwires and branch microstructures can be integrated into the C/S and branch C/S structures, respectively. Significantly, the integrated branch C/S microwires, with multicolor waveguide behavior and branch structure multichannel waveguide output characteristics, can function as an optical logic gate with multiple encoding features. This work provides useful insights for creating completely new types of organic microstructures for integrated optoelectronics.
Keywords:Hierarchical Self-Assembly  Integrated Photonics  Low-Dimensional Structures  Noncovalent Interactions  Organic Semiconductors
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