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Synthesis of Tetraarylethene Luminogens by C?H Vinylation of Aromatic Compounds with Triazenes
Authors:Abdusalom A Suleymanov  Martin Doll  Dr Albert Ruggi  Dr Rosario Scopelliti  Dr Farzaneh Fadaei-Tirani  Prof Kay Severin
Institution:1. Institut des Sciences et Ingénierie Chimiques, Ecole Polytechnique Fédérale de Lausanne (EPFL), 1015 Lausanne, Switzerland;2. Département de Chimie, Université de Fribourg, 1700 Fribourg, Switzerland
Abstract:Tetraarylethenes are obtained by acid-induced coupling of vinyl triazenes with aromatic compounds. This new C?H activation route for the synthesis of aggregation-induced emission luminogens is simple, fast, and versatile. It allows the direct grafting of triarylethenyl groups onto a variety of aromatic compounds, including heterocycles, supramolecular hosts, biologically relevant molecules, and commercial polymers.
Keywords:Aggregation  Fluoreszenz  Tetraarylethene  Synthesemethoden  Vinylierungen
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