N-Doping of Polyaromatic Capsules: Small Cavity Modification Leads to Large Change in Host–Guest Interactions |
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Authors: | Hiroki Dobashi Dr Lorenzo Catti Dr Yuya Tanaka Prof Dr Munetaka Akita Prof Dr Michito Yoshizawa |
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Institution: | 1. Laboratory for Chemistry and Life Science, Institute of Innovative Research, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama, 226-8503 Japan;2. WPI Nano Life Science Institute, Kanazawa University, Kakuma-machi, Kanazawa, 920-1192 Japan |
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Abstract: | To gain insight into the host functions of a nanocavity encircled by both polyaromatic panels and heteroatoms, nitrogen-doped polyaromatic capsules were successfully synthesized from metal ions and pyridine-embedded, bent anthracene-based ligands. The new capsules display unique host–guest interactions in the isolated cavities, which are distinct from those of the undoped analogues. Besides the inclusion of Ag+ ions, the large absorption change of fullerene C60 and altered emission of a BODIPY dimer are observed upon encapsulation by the present hosts. Moreover, the N-doped capsule exhibits specific binding ability toward progesterone and methyltestosterone, known as a natural female and synthetic male hormone, respectively, in water. |
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Keywords: | fluorescence host-guest systems noncovalent interactions polyaromatics supramolecular chemistry |
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