| 4，4＇－偶氮二［4－氰基戊酰（对－二甲氨基）苯胺］作为引发剂的嵌段共聚物合成 |
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| 引用本文： | 邱醒宇,魏峰,关宏宇,平学真.4，4＇－偶氮二［4－氰基戊酰（对－二甲氨基）苯胺］作为引发剂的嵌段共聚物合成[J].高分子学报,1994(4). |
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| 作者姓名： | 邱醒宇 魏峰 关宏宇 平学真 |
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| 作者单位： | 辽宁大学化学系 |
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| 摘 要： | ４，４＇－偶氮二［４－氰基戊酰（对－二甲氨基）苯胺］作为引发剂的嵌段共聚物合成邱醒宇，魏峰，关宏宇，平学真（辽宁大学化学系，沈阳，１１００３６）关键词４，４＇－偶氮二［４－氰基戊酰（对－二甲氨基）苯胺］，多官能团引发剂，自由基聚合７０年代以来，陆续报...
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| 关 键 词： | 4，4＇－偶氮二［4－氰基戊酰（对－二甲氨基）苯胺］，多官能团引发剂，自由基聚合 |
A SYNTHESIS METHOD FOR BLOCK POLYMERS USING 4,4'-AZOBIS-[4-CYANOPENTANOYL (p-DIMETHYLAMINO)ANILIDE] AS INITIATOR |
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| QIU Xingyu, WEI Feng, GUAN Hongyu, PING Xuezhen.A SYNTHESIS METHOD FOR BLOCK POLYMERS USING 4,4''''-AZOBIS-[4-CYANOPENTANOYL (p-DIMETHYLAMINO)ANILIDE] AS INITIATOR[J].Acta Polymerica Sinica,1994(4). |
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| Authors: | QIU Xingyu WEI Feng GUAN Hongyu PING Xuezhen |
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| Abstract: | his paper describes a new polyfimctional inihator, 4,4'-azobis4-cyanopentanoyl (p-dimethylandno)anilide] (ACPDA), for the the radical polymerization. It was obtained by the rcaction of 4,4'-azobis(4-cyanopentanoyl chloride) with p-amino-N, N-dimethylaniline' ACPDA contains two reaction centres with different reactvities that are azo-group and N, N-dimethylaniline-group. By the controlled different conditions this initator can be utilized to make block polymers. |
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| Keywords: | Block polymer Polyfunctional initiator Free radical polymerization |
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