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| 呋喃甲基缩水甘油醚与二氧化碳的共聚反应研究 | |
| 引用本文： | 侯继强,乔立军,魏军,胡玉玺,王献红,赵晓江,王佛松.呋喃甲基缩水甘油醚与二氧化碳的共聚反应研究[J].高分子学报,2009,0(10):1007-1011. |
| 作者姓名： | 侯继强 乔立军 魏军 胡玉玺 王献红 赵晓江 王佛松 |
| 作者单位： | 1. 中国科学院长春应用化学研究所高分子物理与化学国家重点实验室,长春,130022;中国科学院研究生院,北京,100039 2. 中国科学院长春应用化学研究所高分子物理与化学国家重点实验室,长春,130022 3. 中国科学院长春应用化学研究所高分子物理与化学国家重点实验室,长春,130022;中国科学院,北京,100864 |
| 摘 要： | 采用糠醇和环氧氯丙烷反应制备了纯度较高的呋喃甲基缩水甘油醚,随后呋喃甲基缩水甘油醚与二氧化碳在稀土三元催化剂Y(CCl3COO)3-甘油-ZnEt2的催化下发生共聚反应,生成侧链为呋喃甲醚侧基的脂肪族聚碳酸酯.共聚物主链结构规整,主要为聚酯结构,数均分子量最高可达13.0×104,共聚物的玻璃化转变温度为-29～-30℃,5wt%起始热分解温度大于231℃. |
| 关 键 词： | 二氧化碳 呋喃甲基缩水甘油醚 聚碳酸酯 共聚反应 |
| 收稿时间： | 2008-10-17 |
COPOLYMERIZATION OF FURFURYL GLYCIDYL ETHER AND CARBON DIOXIDE |
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| HOU Jiqiang,QIAO Lijun,WEI Jun,HU Yuxi,WANG Xianhong,ZHAO Xiaojiang,WANG Fosong.COPOLYMERIZATION OF FURFURYL GLYCIDYL ETHER AND CARBON DIOXIDE[J].Acta Polymerica Sinica,2009,0(10):1007-1011. | |
| Authors: | HOU Jiqiang QIAO Lijun WEI Jun HU Yuxi WANG Xianhong ZHAO Xiaojiang WANG Fosong |
| Institution: | Polymer Material and Engineering Laboratory, Changchun Insititute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, Graduate School of Chinese Academy of Science, Beijing 100039, Chinese Academy of Sciences, Beijing 100864 |
| Abstract: | To explore the non-petroleum route for carbon dioxide copolymers,furfuryl glycidyl ether oxirane with 99.7% purity was prepared from furfuryl alcohol and epichlorohydrin employing sodium hydroxide and tert-butylammonium sulfate as catalysts,where furfuryl alcohol was a hydrogenation product of furfural from pentose-rich agricultural residues like rice hulls,bagasse,corn cob,et al.,and epichlorohydrin could be produced from glycerine which was a byproduct in bio-diesel production.Copolymerization of carbon d... |
| Keywords: | Carbon dioxide Furfuryl glycidyl ether Polycarbonate Copolymerization |
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