| 高分子镍催化剂催化甲醇羰基化制备乙酸 |
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| 引用本文： | 潘平来,柳忠阳,黄茂开,袁国卿.高分子镍催化剂催化甲醇羰基化制备乙酸[J].高分子学报,1995,0(5):632-635. |
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| 作者姓名： | 潘平来 柳忠阳 黄茂开 袁国卿 |
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| 作者单位： | 中国科学院化学研究所 |
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| 摘 要： | 高分子镍催化剂催化甲醇羰基化制备乙酸潘平来，柳忠阳，黄茂开，袁国卿（中国科学院化学研究所北京１０００８０）关键词高分子镍催化剂，羰基化醇类的谈基化反应早在５０年代初就开始研究，ＲｅＰＰｌｅ［Ｕ等人研究发现周期表中第八族金属元素的藏基化物对甲醇谈基化有...
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| 关 键 词： | 高分子镍催化剂，羰基化 |
| 收稿时间： | 1994-11-29 |
STUDY OF CARBONYLATION OF METHANOL TO ACETIC ACID CATALYZED BY A POLYMER-NICKEL COMPLEX |
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| PAN Ping-lai,LIU Zhong-yang,HUANG Mao-kai,YUAN Guo-qing.STUDY OF CARBONYLATION OF METHANOL TO ACETIC ACID CATALYZED BY A POLYMER-NICKEL COMPLEX[J].Acta Polymerica Sinica,1995,0(5):632-635. |
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| Authors: | PAN Ping-lai LIU Zhong-yang HUANG Mao-kai YUAN Guo-qing |
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| Institution: | Institute of Chemistry; Academia Sinica; Beijing; 100080 |
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| Abstract: | nickel complex of linear 2-vinylpyridine-Methyl Acrylate copolymers has been found to be able to catalyze the carbonylation of methanol to produce acetic acid in a mild conditions. Experimental results show that the polymer-nickel complex contains two kinds of coordination bonds, N→Ni and O→Ni.Catalytic activity of the complex is increasing with the augmentation of O→Ni bond.And it also shows that the complex has a resistant effect on poisoning of suphur compounds. |
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| Keywords: | Polymer-Nickel catalyst Carbonylation |
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