| 新型热反应大分子单体的合成与表征 |
| |
| 引用本文： | 杨柏,李英俊,沈家.新型热反应大分子单体的合成与表征[J].高分子学报,1989,0(3):280-284. |
| |
| 作者姓名： | 杨柏 李英俊 沈家 |
| |
| 作者单位： | 吉林大学化学系 长春
(杨柏，李英俊)，吉林大学化学系 长春(沈家(马总)) |
| |
| 摘 要： | 溶液法合成了一些低分子量的羟端基低聚苯醚砜,并由相转移催化剂将之转为热反应大分子单体——α,ω-双甲基丙烯酸聚苯醚砜酯;用FTIR、~1H-NMR对其结构进行了表征,GPC、VPO对其分子量进行了分析和测定;用DSC、DTA对聚苯醚砜双烯大分子单体的转变温度、热反应过程进行了测定和分析。
|
| 关 键 词： | 羟端基低聚苯醚砜 α ω-双甲基丙烯酸聚苯醚砜酯 热反应大分子单体 |
| 收稿时间： | 1987-06-09 |
SYNTHESIS AND CHARACTERIZATION OF NEW CLASS THERMALLY REACTIVE MACROMER |
| |
| YANG Bai,LI Ying-jun,SHEN Jia-cong.SYNTHESIS AND CHARACTERIZATION OF NEW CLASS THERMALLY REACTIVE MACROMER[J].Acta Polymerica Sinica,1989,0(3):280-284. |
| |
| Authors: | YANG Bai LI Ying-jun SHEN Jia-cong |
| |
| Institution: | Jilinn University; Changchun |
| |
| Abstract: | Series of hydroxy-terminated poly(ether-sulfone)s oligomer with different molecular weights were synthesized in solvent, then were transformed into a,w-bis (methacrylate)poly (ether-sulone)s macromer by phase transfer catalyst. Their structure and functionility was characterized with FTIR spectrum, 1H-NMR spectroscopy. Their molecular weight was determined with VPO and GPC. Thermalanalysis of this macromer demonstrates its thermal reactivity. |
| |
| Keywords: | hydroxy-terminated poly(ether-sulfone)s oligomer a w-Bis(methacrylate)poly(ether-sulfone)s Thermally reactive macromer |
| 本文献已被 CNKI 维普 等数据库收录！ |
| 点击此处可从《高分子学报》浏览原始摘要信息 |
| 点击此处可从《高分子学报》下载免费的PDF全文 |
