| 表面富集季胺盐的交联聚苯乙烯微球合成与表征及其溶胀行为研究 |
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| 引用本文： | 陈鑫,陈志民,崔占臣,张恺,张刚,杨柏.表面富集季胺盐的交联聚苯乙烯微球合成与表征及其溶胀行为研究[J].高分子学报,2003(2):293-297. |
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| 作者姓名： | 陈鑫 陈志民 崔占臣 张恺 张刚 杨柏 |
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| 作者单位： | 超分子结构与材料教育部重点实验室,吉林大学化学学院,长春,130023 |
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| 基金项目： | 国家重点基础研究专项经费资助项目 (项目号G19990 64 80 3 ) |
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| 摘 要： | 在聚合物微球表面引入不同的基团 (如亲水性的羟基或羧基 ) ,可以改善聚合物微球的稳定性甚至生物相容性1～ 4] ;利用表面基团可以把无机半导体微粒和功能有机分子以及生物分子引入聚合物微球5～ 8] ,赋予聚合物微球特殊的性能 ,使其广泛应用于涂料、光电功能材料和生物医用材料等领域9～ 15] .其中 ,表面带有阳离子的聚合物微球在絮凝剂、胶粘剂、水性涂料等方面已经得到广泛研究16～ 2 0 ] .通常阳离子聚合物微球可以根据不同的需要利用常规乳液聚合、核壳乳液聚合等方法来合成 .亲水性和疏水性单体进行的无皂乳液聚合2 1] ,因其能在…
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| 关 键 词： | 无皂乳液聚合 季胺盐 原位溶胀 |
| 修稿时间： | 2002年5月30日 |
SYNTHESIS AND CHARACTERIZATIONS OF CROSS-LINKED POLYSTYRENE MICROSPHERES WITH QUARTERNARY AMMONIUM ON THE SURFACE AND STUDIES ON THEIR SWELLING BEHAVIOR |
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| CHEN Xin,CHEN Zhimin,CUI Zhanchen,ZHANG Kai,ZHANG Gang,YANG Bai.SYNTHESIS AND CHARACTERIZATIONS OF CROSS-LINKED POLYSTYRENE MICROSPHERES WITH QUARTERNARY AMMONIUM ON THE SURFACE AND STUDIES ON THEIR SWELLING BEHAVIOR[J].Acta Polymerica Sinica,2003(2):293-297. |
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| Authors: | CHEN Xin CHEN Zhimin CUI Zhanchen ZHANG Kai ZHANG Gang YANG Bai |
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| Abstract: | Cross linked polystyrene microspheres with quarternary ammonium have been prepared via surfactant\|free emulsion polymerization. It was confirmed that the sizes of the microspheres decreased at a certain extent when the contents of the initiator,cross linked reagent or functional monomer were increased.TEM observation indicated that the size of polymer microspheres ranged from tens of nanometer to hundreds of nanometer. The XPS results showed that the hydrophilic quarternary ammonium groups tended to be rich on the surface of the microspheres during the polymerization.In addition,their swelling ratio can be investigated by using the “ in situ" swelling measurement of polymer microspheres. |
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| Keywords: | Surfactant free emulsion polymerization Quarternary ammonium in situ Swelling |
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