| 用一氧化碳阻聚法对丙烯气相聚合动力学的研究 |
| |
| 引用本文： | 李于飞,唐士培.用一氧化碳阻聚法对丙烯气相聚合动力学的研究[J].高分子学报,1986,0(2):137-143. |
| |
| 作者姓名： | 李于飞 唐士培 |
| |
| 作者单位： | 北京化工研究院 北京
(李于飞)，北京化工研究院 北京(唐士培) |
| |
| 摘 要： | 本文研究了一种新的烯烃聚合活性中心浓度测定方法,即CO阻聚法,并在此基础上测定了络合型催化剂丙烯气相聚合的活性中心浓度、链增长速度常数及活化能;证实了该方法用于丙烯气相聚合的可靠性及其主要影响因素是CO对活性中心的“多次阻聚”,同时从实验上证明丙烯聚合速度衰减是由于活性中心浓度降低。
|
| 收稿时间： | 1983-12-30 |
KINETIC STUDY OF GAS-PHASE POLYMERIZATION OF PROPENE BY THE INHIBITION METHOD USING CARBON MONOXIDE |
| |
| LI Yu-fei,TANG Shi-pei.KINETIC STUDY OF GAS-PHASE POLYMERIZATION OF PROPENE BY THE INHIBITION METHOD USING CARBON MONOXIDE[J].Acta Polymerica Sinica,1986,0(2):137-143. |
| |
| Authors: | LI Yu-fei TANG Shi-pei |
| |
| Institution: | Beijing Research Institute of Chemical Industry; Beijing |
| |
| Abstract: | The inhibition method using CO to determine the active center concentration C in gas-phase polymerization of propene were studied. The method is found to be also reliable when used in gas-phase polymerization and mainly affected by the "repeating inhibition" of CO to the active centers. It is proved experimentally that polymerization rate decay coincides with the decrease of C. |
| |
| Keywords: | |
| 本文献已被 CNKI 等数据库收录！ |
| 点击此处可从《高分子学报》浏览原始摘要信息 |
| 点击此处可从《高分子学报》下载免费的PDF全文 |
