| 田菁胶负载钯催化Heck反应的研究 |
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| 引用本文： | 崔元臣,张磊.田菁胶负载钯催化Heck反应的研究[J].高分子学报,2005(3):423-426. |
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| 作者姓名： | 崔元臣 张磊 |
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| 作者单位： | 河南大学化学化工学院,开封,475001 |
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| 摘 要： | 通过较简单的方法合成了田菁胶负载钯化合物,利用XPS、IR、TG、DTA和TEM等手段对其进行了表征.该化合物在空气氛围中就能很好地催化丙烯酸、苯乙烯和丙烯酰胺与芳基碘的Heck反应,高产率(≥85 % )且立体选择性地生成取代的反式肉桂酸、1,2- 二苯乙烯和肉桂酰胺.化合物具有较好的重复使用性能.催化剂中起催化作用的是金属态的钯.
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| 关 键 词： | 田菁胶 钯 负载型催化剂 Heck反应 |
| 修稿时间： | 2004年3月9日 |
STUDIES ON THE CATALYSIS OF SESBANIA GUM SUPPORTED PALLADIUM COMPOUND FOR HECK REACTION |
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| Cui Yuanchen,ZHANG Lei.STUDIES ON THE CATALYSIS OF SESBANIA GUM SUPPORTED PALLADIUM COMPOUND FOR HECK REACTION[J].Acta Polymerica Sinica,2005(3):423-426. |
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| Authors: | Cui Yuanchen ZHANG Lei |
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| Abstract: | Sesbania gum supported palladium compound was synthesized with simple method and characterized by XPS,IR,TG,DTA,TEM etc.It was found that the sesbania gum s uppo rted palladium compound is an efficient catalyst for Heck reaction of acrylic ac id,styrene and acrylamide with aryl iodide such as iodobenzene, 4-iodotoluen e, 4-iodoanisole, 1-chloro-4-iodobenzene at atmospheric condition.The substi tuted trans-cinnamic acid,trans-stilbene and trans-cinnamoylamide was obtai ned in high yield (≥85%).The sesbania gum supported palladium compound can be u sed repeatedly in the Heck reaction.The active center of the catalyst is metalli c Pd. |
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| Keywords: | Sesbania gum Palladium Supported catalyst Heck reaction |
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