| 阴离子型含氟两亲接枝共聚物的合成及其胶束化行为研究 |
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| 引用本文： | 刘国强,熊圣东,张凌飞,易昌凤,徐祖顺.阴离子型含氟两亲接枝共聚物的合成及其胶束化行为研究[J].高分子学报,2011(12):1402-1411. |
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| 作者姓名： | 刘国强 熊圣东 张凌飞 易昌凤 徐祖顺 |
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| 作者单位： | 湖北大学材料科学与工程学院;湖北大学功能材料绿色制备与应用教育部重点实验室; |
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| 基金项目： | “十一五”国家科技重点支持计划(项目号2008BAC32B03); 湖北省科技厅创新群体基金(基金号2010CDA077)资助项目 |
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| 摘 要： | 以聚乙二醇甲醚甲基丙烯酸酯(MPEGMA)为大分子单体,甲基丙烯酸六氟丁酯(HFMA)、对苯乙烯磺酸钠(NaSS)为共聚单体,采用大分子单体接枝共聚法,制备了一种阴离子型含氟两亲接枝共聚物P( HFMA-co-NaSS) -g-PEG.利用FTIR、1H-NMR和19F-NMR对共聚物的分子结构进行了表征.表面张力法测...
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| 关 键 词： | 阴离子 两亲接枝共聚物 胶束化行为 含氟聚合物 荧光光谱 牛血清蛋白 |
SYNTHESIS AND MICELLIZATION BEHAVIOR OF ANIONIC FLUORINE-CONTAINING AMPHIPHILIC GRAFT COPOLYMERS |
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| LIU Guoqiang,XIONG Shengdong,ZHANG Lingfei,YI Changfeng,XU Zushun.SYNTHESIS AND MICELLIZATION BEHAVIOR OF ANIONIC FLUORINE-CONTAINING AMPHIPHILIC GRAFT COPOLYMERS[J].Acta Polymerica Sinica,2011(12):1402-1411. |
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| Authors: | LIU Guoqiang XIONG Shengdong ZHANG Lingfei YI Changfeng XU Zushun |
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| Institution: | LIU Guoqiang1,XIONG Shengdong1,ZHANG Lingfei1,YI Changfeng1,2,XU Zushun1,2(1 College of Materials Science and Engineering,Hubei University,Wuhan 430062)(2 Ministry-of-Education Key Laboratory f or the Green Preparation and Application of Functional Materials,Wuhan 430062) |
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| Abstract: | A novel series of anionic fluorine-containing amphiphilic graft copolymers P(HFMA-co-NaSS)-g-PEG were synthesized by graft copolymerization of poly(ethylene glycol) methyl ether methacrylate(MPEGMA) macromonomer,2,2,3,4,4,4-hexafluorobutyl methacrylate(HFMA) and sodium 4-vinylbenzenesulfonate(NaSS).The molecular structures of the amphiphilic graft copolymer were characterized by FTIR,1H-NMR and 19F-NMR.The critical micelle concentration(CMC) of P(HFMA-co-NaSS)-g-PEG was measured by surface tension technique... |
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| Keywords: | Anionic Amphiphilic graft copolymer Micellization Fluoropolymer Fluorescence spectroscopy Bovine serum albumin |
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