| 丙烯酸酯共聚物乳液自交联反应的研究 |
| |
| 引用本文： | 程时远,徐祖顺,张洪涛,陈沛智,李建宗.丙烯酸酯共聚物乳液自交联反应的研究[J].高分子学报,1992,0(2):142-147. |
| |
| 作者姓名： | 程时远 徐祖顺 张洪涛 陈沛智 李建宗 |
| |
| 作者单位： | 湖北大学高分子材料研究室，湖北大学高分子材料研究室，湖北大学高分子材料研究室，湖北大学高分子材料研究室，湖北大学高分子材料研究室 武汉，邮政编码:430062，武汉，邮政编码:430062，武汉，邮政编码:430062，武汉，邮政编码:430062，武汉，邮政编码:430062 |
| |
| 摘 要： | 本文研究了含环氧基的丙烯酸酯四元共聚物乳液交联后的溶胀度、自交联反应及动力学.结果表明:交联共聚物的溶胀度Q随甲基丙烯酸环氧丙酯单体含量的增加而降低,共聚物在受热的情况下,环氧基因在羧基的作用下开环而发生交联反应,产生网状结构.
|
| 关 键 词： | 自交联反应 丙烯酸酯 聚合物乳液 活性单体 |
| 收稿时间： | 1991-04-10 |
STUDY ON SELF-CROSSLINKING REACTION OF ACRYLATES COPOLYMER EMULSION |
| |
| CHENG Shi-yuan,XU Zu-shun,ZHANG Hong-tao,CHEN Pei-zhi,LI Jiang-zong.STUDY ON SELF-CROSSLINKING REACTION OF ACRYLATES COPOLYMER EMULSION[J].Acta Polymerica Sinica,1992,0(2):142-147. |
| |
| Authors: | CHENG Shi-yuan XU Zu-shun ZHANG Hong-tao CHEN Pei-zhi LI Jiang-zong |
| |
| Institution: | Chemistry Department; Hubei University; Wuhan; Post code: 430062 |
| |
| Abstract: | The emulsion of copolymers of acrylates with epoxy group were preparedand characterized by means of swelling capacity. The self crosslinkingreaction of the copolymer was studied by FT-IR. It has been found that theswelling capacity of the crosslinked copolymer films decreased with increaseof the glycidyl methacrylate (GMA) content. The activation energy of thecrosslin-king reaction was obtained. A mechanism of the crosslinking reactionwas proposed. |
| |
| Keywords: | Self-crosslinking reaction Acrylates Polymer emulsion Active monomer |
| 本文献已被 CNKI 维普 等数据库收录！ |
| 点击此处可从《高分子学报》浏览原始摘要信息 |
| 点击此处可从《高分子学报》下载免费的PDF全文 |
