| 聚酯酰胺的合成及表征 |
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| 引用本文： | 竺朝山,武荣瑞.聚酯酰胺的合成及表征[J].高分子学报,1995(3). |
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| 作者姓名： | 竺朝山 武荣瑞 |
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| 作者单位： | 北京市化工研究院，北京服装学院 |
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| 摘 要： | 用两种方法合成了聚酯酰胺（ＰＥＡ）共聚物．一种是两步法，即先合成对苯二甲酸乙醇酰胺（ＢＡＥＴ）单体，然后与对苯二甲酸乙二酯（ＢＨＥＴ）共缩聚；另一种是一步法．即在酯交换反应中直接添加乙醇胺（ＥＡ）．两种方法制得的聚酯酰胺（ＰＥＡ）共聚物测试证明了为产物，并分析了合成中的化学反应．
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| 关 键 词： | 聚酯酰胺，对苯二甲酸乙醇酰胺，乙醇胺，共聚反应 |
THE SYNTHESIS AND CHARACTERIZATION OF THE POLYESTERAMIDE |
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| ZHU Chaoshan.THE SYNTHESIS AND CHARACTERIZATION OF THE POLYESTERAMIDE[J].Acta Polymerica Sinica,1995(3). |
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| Authors: | ZHU Chaoshan |
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| Abstract: | The polyesteramide (PEA) is synthesized by two methods.One of them is two-step method,firstly BAET and BHET are synthesized from the reactions of DMT (dimethyl therephthalate) with EA (ethanolamine) and TPA(terephthalic acid) with EG (ethylene glycol),reapectively;then BAET and BHET are condensation copolymerized.The chemical structure of the BAET is characterized by IR,IH--NMR and GC--MS.Another is one--step method that is synthesized by copolycondensation of DMT,EG and EA directly.All of the copolymers are characterized by the determination of nitrogen content,IR and NMR,The chemical reactions procssaes are discussed. |
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| Keywords: | Polyesteramide Terephthalate-bis-N-(2-hydroxyethly)-amide Ethanolamine Copolycondensation |
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