| 1,2-二乙炔基四苯基乙硅烷与1,2-二乙炔基四甲基乙硅烷的共聚及其光解 |
| |
| 引用本文： | 洪仁芳,石川满夫.1,2-二乙炔基四苯基乙硅烷与1,2-二乙炔基四甲基乙硅烷的共聚及其光解[J].高分子学报,1993,0(6):667-671. |
| |
| 作者姓名： | 洪仁芳 石川满夫 |
| |
| 作者单位： | 北京化工学院应用化学系; 广岛大学工学部 |
| |
| 摘 要： | １，２－二乙炔基四苯基乙硅烷与１，２－二乙炔基四甲基乙硅烷在催化剂铑（Ⅰ）络合物［氯化三－（三苯基膦）铑］的作用下得到一种新的含硅共聚物。实验证明此共聚物的主链是有规交替结构。研究了固体薄膜及其溶液的光解作用，并测定了ＳｂＦ５蒸气处理后的共聚物薄膜的导电性。
|
| 关 键 词： | 二乙炔基 四苯基 乙硅烷 共聚 光解 |
| 收稿时间： | 1991-09-02 |
SYNTHESIS OF COPOLYMER FROM 1,2-DIETHYNYLTETRA- PHENYIDISILANE AND 1,2-DIETHYNYLTETRAMETHYLDISILANE AND ITS PHOTOLYSIS |
| |
| HONG Ren-fang,MITSUO Ishikawa.SYNTHESIS OF COPOLYMER FROM 1,2-DIETHYNYLTETRA- PHENYIDISILANE AND 1,2-DIETHYNYLTETRAMETHYLDISILANE AND ITS PHOTOLYSIS[J].Acta Polymerica Sinica,1993,0(6):667-671. |
| |
| Authors: | HONG Ren-fang MITSUO Ishikawa |
| |
| Institution: | Department of Applied Chemistry Beijing Institute of Chemical Technology; Beijing; Post code: 100029; Department of Applied Chemistry; Faculty of Engineering; Hiroshima University |
| |
| Abstract: | A new copolymer was synthesized by 1, 2-diethynyltetraphenyldisilane and 1, 2-di-ethynyltetramethyldisilane with a catalytic amount of a rhodium ( I ) complex. We have found that this copolymer has regular alternating arrangement in the copolymer backbone. The photochemical behavior has been examined in solid film and in solution of the copolymer. The film was treated with SbF5 vapour. And its conductivity was measured. |
| |
| Keywords: | |
| 本文献已被 维普 等数据库收录！ |
| 点击此处可从《高分子学报》浏览原始摘要信息 |
| 点击此处可从《高分子学报》下载免费的PDF全文 |
