马来酸酐-苯乙烯多组分单体熔融接枝高密度聚乙烯机理及性能研究

用单螺杆挤出机制备了马来酸酐-苯乙烯(MAH-St)多单体熔融接枝高密度聚乙烯(HDPE)体系,研究发现添加St共同接枝,可以显著提高接枝物的接枝率.随着St的增加,接枝率先增大后有所降低.当两种单体物质的量比约为1:1时,接枝物的接枝率最高,此时接枝物的熔体流动速率(MFR)最小.即MAH接枝率越高,接枝物的MFR越...

STYRENE ASSISTED MELT FREE RADICAL GRAFTING OF MALEIC ANHYDRIDE ONTO HIGH DENSITY POLYETHYLENE AND PROPERTIES OF THE GRAFT COPOLYMER

Free radical melt-grafting of the multi-monomer system of maleic anhydride(MAH) /styrene(St) onto high density polyethylene(HDPE) prepared by a single-screw extruder was studied.It was found that the addition of St monomer could significantly improve the MAH grafting level of the grafted HDPE.With increasing the St concentration,the graft degree of MAH first increased and then decreased a little.The maximum MAH grafting degree and the minimum melt flow rate were obtained when the molar ratio of MAH to St was approximately 1∶ 1.The higher the graft degreet,he smaller MFR value was,suggesting that the grafted PE chains induced intermolecular entanglements.The mechanical properties of the grafted polymer with the addition of small portions of St monomer were better than those of the neat HDPE in this case.The mechanism of the multi-monomer melt grafting HDPE system was also discussed.It was proposed that MAH and St interacted and copolymerized with each other in the melt grafting system.The grafting of St-MAH copolymer(SMA) onto HDPE greatly increased the grafting degree of the grafted HDPE.When the amount of St is larger than MAH,St would be first grafted onto the PE backbonei,nhibiting the grafting of SMA.Besidest,he cross-linking of PE was well depressed due to the increase of graft degree in the multi-monomer melt grafting systems.And no obvious gel was obseved in the reflux process.