超临界甲醇降解对苯二甲酸丁二酯的研究

作为一种综合性能优良的新型工程塑料，对苯二甲酸丁二酯(PBT)工程塑料及其各种合金在全球范围内已经广泛用于电子电气、汽车、机械及民用等各个领域，而中国是其中需求量最大的国家．

DEPOLYMERIZATION OF POLYBUTYLENE TEREPHTHALATE IN SUPERCRITICAL METHANOL

Depolymerization of polybutylene terephthalate (PBT) in supercritical methanol was studied using a stainless stirred batch\|type autoclave under high temperature (453～533?K) and high pressure (7～12?MPa) conditions.The main depolymerization products were dimethyl terephthalate (DMT) monomer and ethylene glycol.The effects of different reaction temperature and pressure on depolymerization of PBT were investigated by analysis of the solid phase and liquid phase products.Considering the critical point of methanol (512 6?K,8 09?MPa),the reaction pressure was varied with in the range of 7～12?MPa.The results showed that the reaction pressure had little influence on the depolymerization and the depolymerization rate was affected greatly by the reaction temperature.The depolymerization of PBT was only 30% in 40?min at lower temperatures (453～463?K) but reached 100% in 20?min when the temperature was above 513?K.Depolymerization kinetics of polybutylene terephthalate in supercritical methanol was studied.The results showed that the depolymerization reaction rate constant ( k 1) in the temperature range of 513～533?K was much larger than the rate constant ( k 2) in the range of 453～483?K.The dissolution characteristics of PBT in supercritical methanol were the critical factors for depolymerization of PBT in a short time.These findings suggest that the supercritical methanol treatment for depolymerization of polymers such as PBT will be potential for obtaining useful chemicals.