| 氧负离子聚合在超支化聚合物合成中的应用 |
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| 引用本文： | 杜娟,周永丰,颜德岳.氧负离子聚合在超支化聚合物合成中的应用[J].高分子学报,2010,0(3):255-267. |
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| 作者姓名： | 杜娟 周永丰 颜德岳 |
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| 作者单位： | 上海交通大学化学化工学院,上海,200240 |
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| 基金项目： | 国家自然科学基金(基金号50633010,20774057,20874060,50873058);;国家基础研究计划(项目号2007CB808000,2009CB930400);;上海市科学技术委员会基础科研基金(基金号07DJ14004);;上海市重点学科建设项目(项目号B202)资助;; |
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| 摘 要： | 近年来,氧负离子聚合得到较快发展,单体种类已经由酯基的β位上含有供电性杂原子的甲基丙烯酸酯类扩展到环氧类、甲基丙烯酸羟酯类单体.氧负离子引发这两类单体聚合,可以得到新型结构的超支化聚合物.对氧负离子引发合成超支化聚合物的机理及其应用进行了综述.
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| 关 键 词： | 氧负离子聚合 超支化聚合物 环氧 甲基丙烯酸羟酯 |
| 收稿时间： | 2009-09-27 |
APPLICATION OF OXYANION-INITIATED POLYMERIZATION IN SYNTHESIS OF HYPERBRANCHED POLYMERS |
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| DU Juan,ZHOU Yongfeng,YAN Deyue.APPLICATION OF OXYANION-INITIATED POLYMERIZATION IN SYNTHESIS OF HYPERBRANCHED POLYMERS[J].Acta Polymerica Sinica,2010,0(3):255-267. |
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| Authors: | DU Juan ZHOU Yongfeng YAN Deyue |
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| Institution: | School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai200240 |
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| Abstract: | Oxyanion-initiated polymerization has been greatly developed in recent years.The monomers have been expanded from methacrylate monomers with a β-positioned donor group in the ester moiety to oxetane monomers and methacrylate monomers with hydroxyl group,and some novel hybranched polymers are obtained.The new progress of oxyanion-initiated polymerization,and its mechanisms and applications in the synthesis of hybranched polymers are summarized in detail. |
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| Keywords: | Oxyanion-initiated polymerization Hyperbranched polymer Oxetane monomer Methacrylate monomer |
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