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形状记忆聚合物热力学本构方程
引用本文:李郑发,王正道,熊志远,畅若妮.形状记忆聚合物热力学本构方程[J].高分子学报,2009(1).
作者姓名:李郑发  王正道  熊志远  畅若妮
作者单位:北京交通大学工程力学所,北京,100044
基金项目:国家自然科学基金,教育部新世纪优秀人才支持计划 
摘    要:借鉴聚合物结晶学相关理论,建立了一个针对该类材料的新的热力学本构关系,通过与已有实验结果相比较,发现理论预测值与实验吻合较好.

关 键 词:形状记忆聚合物  热力学  本构方程

THERMOMECHANICAL CONSTITUTIVE EQUATIONS OF SHAPE MEMORY POLYMERS
LI Zheng-fa,WANG Zheng-dao,XIONG Zhi-yuan,CHANG Ruo-ni.THERMOMECHANICAL CONSTITUTIVE EQUATIONS OF SHAPE MEMORY POLYMERS[J].Acta Polymerica Sinica,2009(1).
Authors:LI Zheng-fa  WANG Zheng-dao  XIONG Zhi-yuan  CHANG Ruo-ni
Institution:Institute of Mechanics;School of Civil Engineering;Beijing Jiao-Tong University;Beijing 100044
Abstract:Since the shape memory and recovery characteristics of shape memory polymers(SMPs)are realized by a certain thermalmechanical cycling process,the thermomechanical constitutive equations are critical for predicting the deformation and recovery of this class of materials at different constraint conditions.In this study,a new physical-based,temperature and time-dependent constitutive model was proposed.The crystallization theory was used for reference to describe the frozen fraction of SMPs,and the frozen reta...
Keywords:Shape memory polymer  Thermomechanics  Constitutive equation  
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