| 聚苯基单醚喹噁啉和铂铑络合物的研究 |
| |
| 引用本文： | 卢凤才,王玉兰,王殿勋,余阳.聚苯基单醚喹噁啉和铂铑络合物的研究[J].高分子学报,1985,0(2):154-156. |
| |
| 作者姓名： | 卢凤才 王玉兰 王殿勋 余阳 |
| |
| 作者单位： | 中国科学院化学研究所
(卢凤才，王玉兰，王殿勋)，北京市营养源研究所(余阳) |
| |
| 摘 要： | <正> 芳杂环高分子是一种耐高温高分子,诸如聚酰亚胺、聚苯基单醚喹噁啉等,都是耐高温优良的高分子,而后者还具有突出的耐高温水解性。鉴于芳杂环高分子主链结构上含N、S或O原子,它们都有未成键的电子,可以作为电子给体,而金属化合物中的金属有空轨道,可以作为电子受体,在合适条件发生电荷转移形成络合物。实验结果表明,聚苯
|
| 收稿时间： | 1983-11-11 |
STUDY OF POLYPHENYLQUINOXALINE-PLATINUM AND RHODIUM COMPLEXES |
| |
| LU Feng-cai,WANG Yu-lan,WANG Dian-xun,YU Yang.STUDY OF POLYPHENYLQUINOXALINE-PLATINUM AND RHODIUM COMPLEXES[J].Acta Polymerica Sinica,1985,0(2):154-156. |
| |
| Authors: | LU Feng-cai WANG Yu-lan WANG Dian-xun YU Yang |
| |
| Institution: | Institute of Chemistry; Academia Sinica; Beijing |
| |
| Abstract: | Two new polyphenylquinoxaline-platinum and rhodium complexes indentified by X-ray photoelectron spectroscopy were synthesized. Their catalytic properties on hy-drosilylation and hydrogenation of unsaturated compounds have been investigated. It was found that these polymer complexes possessed high calalytic activities and could be easily recocvered after each reaction and repeatedly used for several times while maintaining the same effectiveness. |
| |
| Keywords: | |
| 本文献已被 CNKI 等数据库收录！ |
| 点击此处可从《高分子学报》浏览原始摘要信息 |
| 点击此处可从《高分子学报》下载免费的PDF全文 |
|
