| 丙烯酸甲酯-氰尿酸三烯丙酯共聚物的合成及其孔结构的研究Ⅰ. |
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| 引用本文： | 张耕宜,郭贤权,张全兴,何炳林.丙烯酸甲酯-氰尿酸三烯丙酯共聚物的合成及其孔结构的研究Ⅰ.[J].高分子学报,1989(2). |
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| 作者姓名： | 张耕宜 郭贤权 张全兴 何炳林 |
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| 作者单位： | 南开大学高分子化学研究所 天津
(张耕宜，郭贤权，张全兴)，南开大学高分子化学研究所 天津(何炳林) |
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| 摘 要： | 氰尿酸三烯丙酯(TAC)与丙烯酸甲酯(MA)在致孔剂如环己烷、正丁醚或甲苯-汽油(200~#)存在下,用悬浮聚合得到一系列大孔共聚物。对这些共聚物孔结构的研究表明,它们的平均孔径达10000—80000(?),同时研完了致孔剂的分子结构和用量对共聚物孔结构的影响,并初步讨论特大孔共聚物形成的机理。
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| 关 键 词： | 氰尿酸三烯丙酯 异氰尿酸三烯丙酯 丙烯酸甲酯 特大孔 |
STUDY ON THE PREPARATION AND PORE STRUCTURES OF COPOLYMER OF TRIALLYL CYANURATE AND METHYL ACRYLATE |
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| ZHANG Gengyi,GUO Xianquan,ZHANG Quanxing and HE Binglin.STUDY ON THE PREPARATION AND PORE STRUCTURES OF COPOLYMER OF TRIALLYL CYANURATE AND METHYL ACRYLATE[J].Acta Polymerica Sinica,1989(2). |
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| Authors: | ZHANG Gengyi GUO Xianquan ZHANG Quanxing and HE Binglin |
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| Abstract: | Copolymer is prepared by the suspension copolymerization of triallyl cyanurate (TAC) and methyl acrylate (MA) in the presence of diluents such as cyclohexane, n-butyl ether, or toluene-gasoline (200#). The pore-structure parameters of the copolymer beads were determined. The study of pore structure shows that average pore radius is 10000-80000 A. The effects of molecular structure and amounts of the diluents on the pore structure of the beads were studied. The mechanism of forming super-macropore was disscused preliminarily. |
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| Keywords: | Triallyl cyanurate Triallyl isocyanurate Methyl acrylate Super-macropore |
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