甲基丙烯酸3-磺酸丙酯钾盐苯乙烯共聚物负离子与N,N,N-三甲基十六烷基溴化铵相互作用研究

聚电解质与表面活性剂相互作用研究已有很多报道1～4],由于在很多方面与生物膜中脂质体-蛋白质间相互作用相似,从而近年来备受关注5～6].作为带电荷的水溶性高分子,聚电解质与带相反电荷的表面活性剂分子可以形成规整性非常好的聚电解质表面活性剂复合物.Ａｎｔｏｎｉｅｔｔｔｉ等报道聚丙烯酸与十六烷基三甲基溴化铵(ＣＴＡＢ)形成规整的介规相(Ｍｅｓｏｐｈａｓｅ)聚电解质表面活性剂复合物结构7],漆宗能等在同一体系既观察到了热致液晶也观察到了溶致液晶8].在研究甲基丙烯酸3磺酸丙酯钾盐(ＳＰＭＳ)的苯乙烯(Ｓｔ)共聚物(Ｐ(ＳＰＭ…

INTERACTION OF CETYLTRIMETHYLAMMONIUM BROMIDE WITH ANIONIC COPOLYMERS OF 3-SULFOPROPYLMETHACRYLATE, POTASSIUM SALT AND STYRENE

The interaction of cetyl trimethylammonium bromide (CTAB)and an anionic copolymer derived from 3\|sulfopropylmethacrylate, potassium salt (SPMS) and styrene (St) in aqueous solutions has been studied. It was found that the viscosity of the anionic copolymer\|CTAB solution rises suddenly in a specific molar ratio of CTAB/anion. For instance, the viscosity of polymer (No.1) solutions increases to about 20 times at CTAB/\|SO\-3K=1.0～1 05, and increases to about 100 times at CTAB/\|SO 3K=1.4～1 5. In the case of polymer samples No.2 and No.3, the changes of solution viscosity are similar to that of sample No.1, but the gelation takes place at CTAB/\|SO\-3K=1.4～1 5 region because of the lower negative charge density on No.2 and No.3 polymer chains. It is proposed that the dramatical change of the P(SPMS-co-St)/CTAB aqueous solution is ascribed to the aggregation behavior of CTAB, then the P(SPMS-co-St) aggregates. This consideration was verified by fluorescence determination and laser light scattering experiments. Using DMAF as fluoresscent probe, the hydrophobic microdomain existed in P(SPMS-co-St)/CTAB aqueous solutions in the viscosity rising region has been confirmed and it is in agreement well with the results obtained by laser light scattering determination.