| 辐射引发丙烯酰胺微乳液聚合 |
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| 引用本文： | 徐相凌,张志成,张曼维.辐射引发丙烯酰胺微乳液聚合[J].高分子学报,1995,0(3):377-379. |
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| 作者姓名： | 徐相凌 张志成 张曼维 |
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| 作者单位： | 中国科学技术大学应用化学系 |
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| 摘 要： | 辐射引发丙烯酰胺微乳液聚合徐相凌，张志成，张曼维（中国科学技术大学应用化学系合肥２３００２６）关键词丙烯酰胺，微乳液聚合，辐射引发聚合聚丙烯酸胺（ＰＡＭ）及其共聚物是广泛应用的水溶性高分子．８０年代中期，Ｃａｎｄａｕ等’‘－”首先开始研究了丙烯酸胺的...
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| 关 键 词： | 丙烯酰胺，微乳液聚合，辐射引发聚合 |
| 收稿时间： | 1994-06-03 |
ACRYLAMIDE MICROEMULSION POLYMERIZATION INITIATED BY γ RAY |
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| XU Xiang-ling,ZHANG Zhi-cheng,ZHANG Man-wei.ACRYLAMIDE MICROEMULSION POLYMERIZATION INITIATED BY γ RAY[J].Acta Polymerica Sinica,1995,0(3):377-379. |
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| Authors: | XU Xiang-ling ZHANG Zhi-cheng ZHANG Man-wei |
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| Institution: | Department of Applied Chemistry; University of Science and Technology of China; Hefei 230026 |
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| Abstract: | he acrylamide microemulsion with the mixture of Span 20 and Tween 80 was initiated with γ ray. The polymerization kinetics were derived:R ∝E]-1.32D]0.55 AM]1.14;Mn∝E]-0.70D]-0.70AM]1.34. There is a constant rate period in microemulsion polymerization. In comparsion with the kinetics in other systems, it is known that it is easier to get partly crosslinked polymacrylamide at higher absorbed dose rate and higher monomer conent. |
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| Keywords: | Acrylamide Microemulsion Radiation polymerization |
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