Aqua(n‐hexyl)[3,3′‐(propane‐1,3‐diyldinitrilo)bis(butan‐2‐one) dioximato‐κ4N]cobalt(III) perchlorate |
| |
Authors: | Ping Xiang Ying Chen Xu‐Jie Shen Hui‐Lan Chen Chun‐Ying Duan |
| |
Abstract: | The title compound, Co(C6H13)(C11H19N4O2)(H2O)]ClO4, is in the general class of coenzyme B12 models which contain a ClO4 anion and a Co(C6H13)(C11H19N4O2)(H2O)]+ cation. In the cation, the Co atom has a distorted octahedral coordination, with the n‐hexyl and H2O ligands in axial positions. The crystal data reveal some degree of flexibility in the Costa‐type system, which is similar to the coenzyme B12. |
| |
Keywords: | |
|
|