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A dinuclear uranium(IV) complex of the chelating ligand 1,2,3,4‐tetra­methyl‐5‐(2‐pyridyl)­cyclo­penta­diene
Authors:Thierry Le Borgne  Pierre Thury  Michel Ephritikhine
Institution:Thierry Le Borgne,Pierre Thuéry,Michel Ephritikhine
Abstract:The ligand 1,2,3,4‐tetra­methyl‐5‐(2‐pyridyl)­cyclo­penta­diene (cp*py) forms a dinuclear complex with UIV, i.e. di‐μ‐oxo‐bis­{chloro­(diethyl ether‐κO)(η5N)‐1,2,3,4‐tetra­methyl‐5‐(2‐pyridyl)­cyclo­penta­dienyl]uranium(IV)}, U2Cl2O2(C14H16N)2(C4H10O)2], in which cp*py acts as a chelating ligand, being bound to the metal atom by the cyclo­penta­dienyl unit and also by the N atom of the pyridyl ring.
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