A dinuclear uranium(IV) complex of the chelating ligand 1,2,3,4‐tetramethyl‐5‐(2‐pyridyl)cyclopentadiene |
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Authors: | Thierry Le Borgne Pierre Thury Michel Ephritikhine |
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Institution: | Thierry Le Borgne,Pierre Thuéry,Michel Ephritikhine |
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Abstract: | The ligand 1,2,3,4‐tetramethyl‐5‐(2‐pyridyl)cyclopentadiene (cp*py) forms a dinuclear complex with UIV, i.e. di‐μ‐oxo‐bis{chloro(diethyl ether‐κO)(η5,κN)‐1,2,3,4‐tetramethyl‐5‐(2‐pyridyl)cyclopentadienyl]uranium(IV)}, U2Cl2O2(C14H16N)2(C4H10O)2], in which cp*py acts as a chelating ligand, being bound to the metal atom by the cyclopentadienyl unit and also by the N atom of the pyridyl ring. |
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