An organometallic RhIII complex with a distorted octahedral structure: (acetonitrile‐κN)dimethyl(1,4,7‐trimethyl‐1,4,7‐triazacyclononane‐κ3N,N′,N′′)rhodium(III) tetraphenylborate |
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| Authors: | Erik Fooladi Bjrn Dalhus Christian Rmming Mats Tilset |
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| Institution: | Erik Fooladi,Bjørn Dalhus,Christian Rømming,Mats Tilset |
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| Abstract: | In the title compound, Rh(CH3)2(C2H3N)(C9H21N3)](C24H20B), the geometry around the RhIII centre is distorted octahedral, with elongated Rh—N bonds trans to the metal‐bonded methyl groups. The metal‐containing cations are located in channels formed by an anionic supramolecular mesh, in which aromatic π–π interactions between anionic B(Ph)4]? units play a major role. |
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