[2,6‐Bis(1H‐benzimidazol‐2‐yl‐κN3)pyridine‐κN](dimethylformamide‐κO)(thiosulfato‐κ2O,S)nickel(II) monohydrate |
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Authors: | Eleonora Freire Sergio Baggio Juan Carlos Muoz Ricardo Baggio |
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Abstract: | The structure of the title compound, Ni(ths)(bbip)(dmf)]·H2O ths is thiosulfate, S2O3; bbip is 2,6‐bis(1H‐benzimidazol‐2‐yl)pyridine, C21H13N5; and dmf is dimethylformamide, C3H7NO], is monomeric, with the nickel ion octahedrally surrounded by an N,N′,N′′‐tridentate bbip molecule, an S,O‐bidentate ths molecule and an O‐monodentate dmf molecule. The H atoms of the hydration water molecule and the amino groups of bbip are involved in hydrogen bonding and determine a spatial organization of broad layers parallel to (001), which are connected by weak interactions. |
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