Magnetically recyclable Schiff-based palladium nanocatalyst [Fe3O4@SiNSB-Pd] and its catalytic applications in Heck reaction |
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Institution: | 1. Department of Chemical Sciences, Bernal Institute, University of Limerick, Limerick V94 T9PX, Ireland;2. Faculty of Science and Natural Resources, Universiti Malaysia Sabah, Kota Kinabalu, 88400 Sabah, Malaysia;3. Department of Chemistry, University of Bahrain, Bahrain;4. School of Engineering, Bernal Institute, University of Limerick, Limerick V94 T9PX, Ireland;5. Department of Applied Science, Technological University of the Shannon: Midlands Midwest, Moylish, Limerick V94 EC5T, Ireland |
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Abstract: | A magnetically separable palladium nanocatalyst has been synthesized through the immobilization of palladium onto 3-aminopropylphenanthroline Schiff based functionalized silica coated superparamagnetic Fe3O4 nanoparticles. The nanocatalyst (Fe3O4@SiNSB-Pd) was fully characterized using several spectroscopic techniques, such as FT-IR, HR-SEM, TEM, XRD, ICP, and XPS. The microscopic image of Fe3O4 showed spherical shape morphology and had an average size of 150 nm. The Pd-nanoparticles exhibited an average size 3.5 ± 0.6 nm. The successful functionalization of Fe3O4@SiNSB-Pd was identified by FT-IR spectroscopy and the appearance of palladium species in Fe3O4@SiNSB-Pd was confirmed by XRD analysis. While XPS has been utilized for the determination of the chemical oxidation state of palladium species in Fe3O4@SiNSB-Pd. Several activated and deactivated arene halides and olefines were employed for Mizoroki-Heck cross-coupling reactions in the presence of Fe3O4@SiNSB-Pd, each of which produced the respective cross-coupling products with excellent yields. The Fe3O4@SiNSB-Pd shows good reactivity and reusability for up to seven consecutive cycles. |
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Keywords: | Magnetic nanoparticles Silica coated Phenanthroline Palladium Schiff-base Heck reaction |
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