| 亚磷酸三乙酯硫化反应历程的GC/MS研究 |
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| 引用本文： | 庞吉海,黄丽茹,吴国旺,戴敦华,朱国政.亚磷酸三乙酯硫化反应历程的GC/MS研究[J].有机化学,1993,13(4):377-382. |
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| 作者姓名： | 庞吉海 黄丽茹 吴国旺 戴敦华 朱国政 |
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| 作者单位： | 北京医科大学分析计算中心，北京医科大学分析计算中心，北京药物化学研究所，北京药物化学研究所，北京药物化学研究所 北京，100083，北京，100083，北京，102205，北京，102205，北京，102205 |
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| 摘 要： | 用气相色谱-质谱联用技术研究了亚磷酸三乙酯和亚磷酸三苯酯与硫反应的机理.研究证明,硫与三价磷化合物的反应只发生在液相状态.
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| 关 键 词： | 苯基 反应机理 乙基 亚磷酸酯 色谱质谱法 硫化反应 |
Study of the reaction mechanisms of Ph~3P and (C~2H~5O)~3P with S~8 by MS and GC/MS |
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| PANG Ji-Hai,HUANG Li-Ru,WU Guo-Wang,DAI Dun-Hua,ZHU Guo-Zheng Analysis & Computation Center,Beijing Medical University, Beijing Institute of Pharmaceutical Chemistry of Beijing, Beijing.Study of the reaction mechanisms of Ph~3P and (C~2H~5O)~3P with S~8 by MS and GC/MS[J].Chinese Journal of Organic Chemistry,1993,13(4):377-382. |
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| Authors: | PANG Ji-Hai HUANG Li-Ru WU Guo-Wang DAI Dun-Hua ZHU Guo-Zheng Analysis & Computation Center Beijing Medical University Beijing Institute of Pharmaceutical Chemistry of Beijing Beijing |
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| Institution: | PANG Ji-Hai,HUANG Li-Ru,WU Guo-Wang,DAI Dun-Hua,ZHU Guo-Zheng Analysis & Computation Center,Beijing Medical University,100083 Beijing Institute of Pharmaceutical Chemistry of Beijing,102205 Beijing |
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| Abstract: | The reaction mechanisms of Ph_3P and (C_2H_5O)_3P with S_8 were studied by MassSpectrometer and Gas Chromatograph-Mass Spectrometer. A previously reported mechanism of thePh_3P-S_8 reaction was supported and a possible mechanism for the Ph_3P-S_8 and (C_2H_5O)_3P-S_8 reactionis tested and verified. |
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| Keywords: | phosphite vulcanization reaction mechanism gas chromatography-mass spectrometry |
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