| 四方向、六方向醚键型分枝状化合物的合成 |
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| 引用本文： | 郭丽,翁玲玲,郑虎.四方向、六方向醚键型分枝状化合物的合成[J].有机化学,1996(6). |
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| 作者姓名： | 郭丽 翁玲玲 郑虎 |
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| 作者单位： | 四川联合大学化工系，华西医科大学药学院，华西医科大学药学院 四川，成都 610065，四川，成都 610041，四川，成都 610041 |
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| 基金项目： | 高等学校博士学科点专项科研基金 |
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| 摘 要： | 本文选用2,4-二羟甲基-1,5-戊二醇和肌醇为四方向及六方向起始核心,通过氧丙基为空间间隔基与带保护基的分支侧链成醚,脱保护后得未端官能团数为原母核两倍的新型有机分子——四方向及六方向醚键型分枝状化合物。
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| 关 键 词： | 四方向及六方向醚键型分枝状化合物 起始核心 醚键 拓扑结构 |
Synthesis of Four - and Six - directional Ether - bond Branched Compounds |
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| GUO Li.Synthesis of Four - and Six - directional Ether - bond Branched Compounds[J].Chinese Journal of Organic Chemistry,1996(6). |
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| Authors: | GUO Li |
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| Abstract: | New organic molecules- the four- and six- directional ether- bond branched compounds were designed and synthesized. 2,4 - dihydroxymethyl - 1,5 pentadiol and inositol used as four - and six - directional initial cores were oxypropylated first in order to decreased steric hindrance, then reacted with branched building blocks, followed by deprotection to give title compounds. The number of the hydroxyl group of the new compounds are twice as that of initial core. |
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| Keywords: | four - and six - directional ether - bond branched compounds initial core ether bond topology |
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