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| 新型光敏剂——系列尾式卟啉二肽的合成与光学性质研究 | |
| 引用本文： | 罗国添,徐庆兵,陈治希,滕莉丽.新型光敏剂——系列尾式卟啉二肽的合成与光学性质研究[J].有机化学,2009,29(9):1434-1439. |
| 作者姓名： | 罗国添 徐庆兵 陈治希 滕莉丽 |
| 作者单位： | 1. 赣南师范学院化学与生命科学学院,赣州,341000;江西省有机药物化学重点实验室,赣州,341000 2. 赣南师范学院化学与生命科学学院,赣州,341000 |
| 基金项目： | 国家自然科学基金，江西自然科学基金 |
| 摘 要： | 以5-(4-氨基苯基)-10,15,20-三苯基卟啉、叔丁氧羰基(Boc)保护的氨基酸为原料合成了系列新型尾式氨基酸卟啉和尾式卟啉二肽, 用核磁、质谱及元素分析对产物进行了表征, 并研究了其光学性质. 结果表明: 所合成的系列尾式卟啉二肽产率高达94%以上, 在可见光的红光部分有强烈的荧光发射. |
| 关 键 词： | 尾式卟啉二肽 合成 光学性质 |
| 收稿时间： | 2008-11-19 |
| 修稿时间： | 2009-1-24 |
Synthesis and Optical Properties of a Series of New Tailed Porphyrinate Dipeptide |
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| Luo Guotian,Xu Qingbing,Chen Zhixi,Teng Lili.Synthesis and Optical Properties of a Series of New Tailed Porphyrinate Dipeptide[J].Chinese Journal of Organic Chemistry,2009,29(9):1434-1439. | |
| Authors: | Luo Guotian Xu Qingbing Chen Zhixi Teng Lili |
| Institution: | ( College of Chemistry and Life Science, Gannan Normal University, Ganzhou 341000) ( Key Laboratory of Organo-Pharmaceutical Chemistry, Jiangxi Province, Ganzhou 341000) |
| Abstract: | A series of new tailed porphyrinate dipeptides were designed and synthesized by the reactions of 5-(4-aminophenyl)-10,15,20-triphenylporphyrin with Boc protected amino acid. The target products and in-termediates were characterized by MS, 1H NMR techniques and elemental analysis, and their optical proper-ties were researched. The yields were up to 94%. The tailed porphyrinate dipeptides have strong fluores-cence emission in the red region of the spectrum. |
| Keywords: | tailed porphyrinate dipeptide synthesis optical property |
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