| 锰卟啉一次氯酸钠模拟体系中由芳醛制备相应羧酸 |
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| 引用本文： | 李存发,郑维忠,王先元,李广年.锰卟啉一次氯酸钠模拟体系中由芳醛制备相应羧酸[J].有机化学,1993(5). |
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| 作者姓名： | 李存发 郑维忠 王先元 李广年 |
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| 作者单位： | 中国科学院成都有机化学研究所，中国科学院成都有机化学研究所，中国科学院成都有机化学研究所，中国科学院成都有机化学研究所 四川、成都，610015 中国科学院上海有机化学研究所金属有机开放实验室，上海，200032，四川、成都，610015 中国科学院上海有机化学研究所金属有机开放实验室，上海，200032，四川、成都，610015 中国科学院上海有机化学研究所金属有机开放实验室，上海，200032，四川、成都，610015 中国科学院上海有机化学研究所金属有机开放实验室，上海，200032 |
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| 摘 要： | 我们前文报道了在金属卟啉-次氯酸钠模拟体系中氧化苯甲醛时,金属卟啉结构与其催化性能的关系,结果表明:四(2.6-二氯)苯基卟啉合锰是稳定性能最好及活性较高的催化剂。本文进一步报道各种因素对反应的影响,并在此基础上提出了由芳醛合成相
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| 关 键 词： | 催化氧化 制备芳酸 金属卟啉 |
The Oxidation Aromatic Aldehydes to Their Corresponding Acids by the Sodium Hypochlorite-Manganese Porphyrin System |
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| LI Cun-Fa,ZHENG Wei-Zhong,WANG Xian-Yuan,LI Guang-Nian Chengdu Institute of Organic Chemistry,Academia Sinica, Chengdu,Sichuan, Laboratory of Organometallic Chemstry.The Oxidation Aromatic Aldehydes to Their Corresponding Acids by the Sodium Hypochlorite-Manganese Porphyrin System[J].Chinese Journal of Organic Chemistry,1993(5). |
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| Authors: | LI Cun-Fa ZHENG Wei-Zhong WANG Xian-Yuan LI Guang-Nian Chengdu Institute of Organic Chemistry Academia Sinica Chengdu Sichuan Laboratory of Organometallic Chemstry |
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| Institution: | LI Cun-Fa,ZHENG Wei-Zhong,WANG Xian-Yuan,LI Guang-Nian Chengdu Institute of Organic Chemistry,Academia Sinica,610015 Chengdu,Sichuan, Laboratory of Organometallic Chemstry,Shanghai Institute of Organic Chemistry,Academia Sinica,200032 Shanghai |
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| Abstract: | The catalytic oxidation of aromatic aldehydes by sodium hypochlorite-manganeseporphyrin complex system has been studied. The effects of some factors such assolvent, reaction temperature, phase transfer catalyst, concentration of manganeseporphyrin,single oxygen donor and the addition method of sodium hypochlorite to the system mentionedabove on the oxidation reaction were investigated. This work provides a new method for pre-paring aromatic acids from their corresponding aldehydes in good yields. |
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| Keywords: | catalytic oxidation preparation of aromatic acids metalloporphyrin |
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