| 5-烃基丙二酸亚异丙酯的Mannich碱与甲基酮的缩合反应 |
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| 引用本文： | 李景华,李祖光.5-烃基丙二酸亚异丙酯的Mannich碱与甲基酮的缩合反应[J].有机化学,2005,25(2):208-209. |
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| 作者姓名： | 李景华 李祖光 |
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| 作者单位： | 1. 浙江工业大学药学院,杭州,310014
2. 浙江工业大学化工与材料学院,杭州,310014 |
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| 摘 要： | 5-烃基丙二酸亚异丙酯的Mannich碱和甲基酮在弱酸如醋酸的存在下, 合成得到缩合产物5-(3-氧代烃基)丙二酸亚异丙酯(3).
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| 关 键 词： | Mannich碱 甲基酮 丙二酸亚异丙酯 缩合反应 |
| 收稿时间： | 2004-5-10 |
| 修稿时间： | 2004年5月10日 |
Condensation of Mannich Base of Isopropylidene 5-Alkylmalonate with Methyl Ketones |
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| LI,Jing-Hua,a LI,Zhu-Guangb.Condensation of Mannich Base of Isopropylidene 5-Alkylmalonate with Methyl Ketones[J].Chinese Journal of Organic Chemistry,2005,25(2):208-209. |
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| Authors: | LI Jing-Hua a LI Zhu-Guangb |
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| Institution: | ( College of Pharmaceutical Sciences, Zhejiang University of Technology, Hangzhou 310014)( College of Chemical Engineering and Materials, Zhejiang University of Technol-ogy, Hangzhou 310014) |
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| Abstract: | Isopropylidene 5-(3-oxo-alkyl)malonates (3) were synthesized by condensation of Mannich base of isopropylidene malonate with methyl ketones in the presence of faint acid, such as acetic acid. |
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| Keywords: | Mannich base isopropylidene malonate methyl ketone condensation |
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