| 脱肟方法的综述 |
| |
| 引用本文： | 赵文超,沙耀武.脱肟方法的综述[J].有机化学,1996,16(2):121-132. |
| |
| 作者姓名： | 赵文超 沙耀武 |
| |
| 作者单位： | 清华大学化学系，清华大学化学系 北京 100084，北京 100084 |
| |
| 摘 要： | 本文就羰基的保护形式之一-肟的脱肟方法作了综述。全面介绍了脱肟基再生为羰基的各种方法之特点, 并将它们分为五大类: 酸性水解脱肟; 还原脱肟;氧化脱肟; 电化学脱肟; 生物化学脱肟。同时出描述了一些反应的机理。
|
| 关 键 词： | 反应机理 裂解 再生 肟 脱肟 |
Review of deoximation methods |
| |
| ZHAO Wen - Chao SHA Yao - Wu.Review of deoximation methods[J].Chinese Journal of Organic Chemistry,1996,16(2):121-132. |
| |
| Authors: | ZHAO Wen - Chao SHA Yao - Wu |
| |
| Abstract: | In this paper, methods of deoximation are reviewed. Oxime was used to protect carbonyl group as one of stable protective groups. Peculiarity of verious deoximation methods for regenerating parent carbonyl group from its oxime have been introduced more widely. These reactions have been classified into five kinds' acid- catalysed hydrolytic, reductive, oxidative, electrochemical, and biochemical. Some deoximation mechanisms are also described. |
| |
| Keywords: | oxime deoximation cleavage regenerationation |
| 本文献已被 CNKI 维普 等数据库收录！ |
| 点击此处可从《有机化学》浏览原始摘要信息 |
| 点击此处可从《有机化学》下载免费的PDF全文 |
