| 双核磺化酞菁铜(Ⅱ)催化氧化α-萘酚 |
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| 引用本文： | 孙强,邓桂胜,姚小华,苏永成,张振权.双核磺化酞菁铜(Ⅱ)催化氧化α-萘酚[J].有机化学,1996,16(1):83-87. |
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| 作者姓名： | 孙强 邓桂胜 姚小华 苏永成 张振权 |
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| 作者单位： | 东北师范大学化学系 |
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| 摘 要： | 本文研究了以乙醇为溶剂, CaCl2为助催化剂, 双核磺化酞菁铜(Ⅱ)催化氧化α-萘酚制备α-萘醌的各种因素。提出了可能的反应机理。
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| 关 键 词： | 紫外分光光度法 乙醇 反应机理 原子吸收分光光度法 高速液体色谱 氯化钙 催化氧化 萘酚 萘醌 磺化酞菁铜 |
Oxidation of α-naphthol catalyzed by binucleus copper sulfophthalocyanine 1. preparation of α-naphthoquinone in ethanol |
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| Abstract: | Various effects on the oxidation of α-naphthol to α- naphthoquinone by oxygen with bi-nucleus copper sulfo-phthalocyanine as catalyst and CaCl2 as co-catalyst were studied. The factors to affect this reaction, such as temperature, the quality of catalyst, co-catalyst and reaction period of time were discussed and a possible reaction mechanism was also proposed. |
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| Keywords: | ULTRAVIOLET SPECTROPHOTOMETRY ETHANOL REACTION MECHANISM ATOMIC ABSORPTION SPECTROPHOTOMETRY HIGH SPEED LIQUID CHROMATOGRAPHY CALCIUM CHLORIDE CATALYTIC OXIDATION NAPHTHALENOL NAPHTHOQUINONE |
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