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结构不对称三芳胺类化合物的合成、表征及性质研究
引用本文:李英俊,赵楠,李丽娜,李春燕,孙淑琴,周晓霞.结构不对称三芳胺类化合物的合成、表征及性质研究[J].有机化学,2012,32(5):949-952.
作者姓名:李英俊  赵楠  李丽娜  李春燕  孙淑琴  周晓霞
作者单位:辽宁师范大学化学化工学院 大连116029
摘    要:以二芳胺和3,5-二甲基碘苯为原料,利用乌尔曼(Ullmann)反应,合成出了4个结构不对称三芳胺衍生物1~4,除了化合物1之外均为新化合物.利用IR,1H NMR,13C NMR,HRMS和元素分析对其结构进行了表征.考察了它们的光学、电化学和热稳定性质.实验结果表明,所合成的4个目标化合物在氯仿稀溶液中发出绿色荧光,具有良好的电化学和热稳定性.所合成的目标化合物是潜在的空穴传输材料及发绿光的材料.

关 键 词:三芳胺  空穴传输材料  合成  性质研究

Synthesis, Characterization and Properties of Some Novel Structural Asymmetric Triarylamines
Li, Yingjun , Zhao, Nan , Li, Lina , Li, Chunyan , Sun, Shuqin , Zhou, Xiaoxia.Synthesis, Characterization and Properties of Some Novel Structural Asymmetric Triarylamines[J].Chinese Journal of Organic Chemistry,2012,32(5):949-952.
Authors:Li  Yingjun  Zhao  Nan  Li  Lina  Li  Chunyan  Sun  Shuqin  Zhou  Xiaoxia
Institution:Li,Yingjun* Zhao,Nan Li,Lina Li,Chunyan Sun,Shuqin Zhou,Xiaoxia(College of Chemistry and Chemical Engineering,Liaoning Normal University,Dalian 116029)
Abstract:Four structural asymmetric triarylamines were synthesized by diarylamines and 3,5-dimethyl-iodobenzene as the starting materials using Ullmann reaction.They are new compounds except the compound 1.The structures of the target compounds were characterized by IR,1H NMR,13C NMR,HRMS and elemental analysis.The optical,electrochemical,and thermal properties were examined.The results indicated that the synthesized compounds emitted green fluorescence in chloroform,and exhibited a good electrochemical and thermal stability.The synthesized triarylamines are potential hole-transporting materials and green-light-emitting materials.
Keywords:triarylamine  hole-transporting material  synthesis  property research
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