| 含二茂铁基的硫代碳酰腙和缩氨基硫脲的合成 |
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| 引用本文： | 黄国生,梁永民,吴骊珠,马永祥.含二茂铁基的硫代碳酰腙和缩氨基硫脲的合成[J].有机化学,1992,12(4):408-411. |
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| 作者姓名： | 黄国生 梁永民 吴骊珠 马永祥 |
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| 作者单位： | 兰州大学化学系，兰州大学化学系，兰州大学化学系，兰州大学化学系 甘肃，兰州，730000，甘肃，兰州，730000，甘肃，兰州，730000，甘肃，兰州，730000 |
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| 摘 要： | 硫代碳酰腙和氨基硫脲衍生物具有一定的生理活性,可作为某些金属离子的特效试剂,本文报道在乙醇-醋酸介质中通过取代氨基硫脲,硫代碳酰腙与不同的二茂铁衍生物缩合,合成了新的缩氨基硫脲和硫代碳酰腙衍生物.
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| 关 键 词： | 乙醇 乙酸 二茂铁 P 缩氨基硫脲 缩合 硫代碳酰腙 |
The synthesis of thiocarbohydrazones and thiosemicarbazones containing ferrocenyl group |
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| HUANG Guo-Sheng,LIANG Yong-min,WU Li-Zhu,MA Yong-xiang.The synthesis of thiocarbohydrazones and thiosemicarbazones containing ferrocenyl group[J].Chinese Journal of Organic Chemistry,1992,12(4):408-411. |
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| Authors: | HUANG Guo-Sheng LIANG Yong-min WU Li-Zhu MA Yong-xiang |
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| Institution: | HUANG Guo-Sheng,LIANG Yong-min,WU Li-Zhu,MA Yong-xiang Department of Chemistry Lanzhou University 73000 Lanzhou,Gansu |
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| Abstract: | Some new thiosemicarbazones and thiocarbohydrazones containing ferrocenyl group R1CMe:NNHC(S)NHR2R1 = h5-C5H5FeC5H4, h5-C5H5FeC5H4COCH2, R2 = Ph, 2-naphthyl], R3CMe:NNHC(S)NHNH2, R3CMe:NNHC(S)NHN:CR4R5 R3 = h5-C5H5FeC5H4; R4 = Me, R5 = h5-C5H5FeC5H4; R4 = H, R5 = 2-C6H4OH; R4 = Me, R5 = 2-hydroxy-4-methylphenyl] have been synthesized by the condensation of appropriate derivatives of ferrocene and thiocarbohydrazide or thiosemicarbazide in EtOH in the presence of AcOH. All compounds have not been reported so far and their structures have been confirmed by elemental anal., 1H NMR and IR. The reaction conditions for the synthesis of these compounds are also discussed. |
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| Keywords: | ferrocene thiocarbohydrazone thiosemicarbazone synthesis |
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