| 过渡金属催化氮杂二环烯烃不对称开环反应的研究进展 |
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| 引用本文： | 程汉超,梁秀丽,李晓璐,龙玉华,杨定乔.过渡金属催化氮杂二环烯烃不对称开环反应的研究进展[J].有机化学,2012,32(3):433-443. |
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| 作者姓名： | 程汉超 梁秀丽 李晓璐 龙玉华 杨定乔 |
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| 作者单位： | 华南师范大学化学与环境学院 广州510006 |
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| 基金项目： | 国家自然科学基金(No.21172081);广东省自然科学基金(No.8251063101000002)资助项目~~ |
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| 摘 要： | 综述了近年来过渡金属催化氮杂二环烯烃的开环反应的研究进展,重点讨论了过渡金属催化剂的种类、亲核试剂的类型、配体、底物氮杂二环烯烃及其衍生物的结构、溶剂和添加剂等因素对开环反应的影响,并对开环反应的可能的机理进行了讨论.
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| 关 键 词： | 氮杂二环烯烃 过渡金属 催化 开环反应 |
Progress in Transition Metal-Catalyzed Asymmetric Ring-Opening Reactions of Azabicyclic Alkenes |
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| Cheng, Hanchao
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Liang, Xiuli
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Li, Xiaolu
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Long, Yuhua
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Yang, Dingqiao.Progress in Transition Metal-Catalyzed Asymmetric Ring-Opening Reactions of Azabicyclic Alkenes[J].Chinese Journal of Organic Chemistry,2012,32(3):433-443. |
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| Authors: | Cheng Hanchao Liang Xiuli Li Xiaolu Long Yuhua Yang Dingqiao |
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| Institution: | Cheng,Hanchao Liang,Xiuli Li,Xiaolu Long,Yuhua Yang,Dingqiao(School of Chemistry and Environment,South China Normal University,Guangzhou 510006) |
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| Abstract: | The recent progress in transition metal-catalyzed ring-opening reactions of azabicyclic alkenes was reviewed focused on the influence of the types of transition metal catalysts,nucleophiles,ligands,the structures of azabicyclic alkenes and its derivatives,solvents and additives on the ring-opening reactions.Moreover,the possible mechanisms of the ring-opening reactions were also discussed. |
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| Keywords: | azabicyclic alkenes transition metal catalyze ring-opening reaction |
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