| N-(6-氯吡啶-3-基)羰基-2-取代芳基磺酰胺的合成、结构及除草活性研究 |
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| 引用本文： | 姜林,李长城,贾立生,路福绥.N-(6-氯吡啶-3-基)羰基-2-取代芳基磺酰胺的合成、结构及除草活性研究[J].有机化学,2006,26(2):203-206. |
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| 作者姓名： | 姜林 李长城 贾立生 路福绥 |
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| 作者单位： | 山东农业大学化学与材料科学学院,泰安,271018 |
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| 基金项目： | 山东省教育厅(No.J01C10)资助项目. |
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| 摘 要： | 通过6-氯吡啶-3-甲酸与2-取代芳基磺酰胺的缩合反应合成了5个N-(6-氯吡啶-3-基)羰基-2-取代芳基磺酰胺化合物3a～3e, 产物结构经元素分析, 1H NMR, IR确证. 由X射线衍射法测定了化合物3a的晶体结构, 该晶体属于三斜晶系, 空间群为 . 以测试除草活性常用的植物玉米、黄瓜和油菜为试材测定了目标化合物的除草活性, 初步试验表明3a～3d有较好的活性, 而且它们对双子叶植物的抑制作用优于对单子叶植物.
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| 关 键 词： | 芳基磺酰胺 合成 晶体结构 除草活性 |
| 收稿时间： | 01 6 2005 12:00AM |
| 修稿时间： | 08 9 2005 12:00AM |
Synthesis, Structure and Herbicidal Activity of N-(6-Chloropyrid- 3-yl)carbonyl-2-substituted Arylsulfona-mides |
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| JIANG, Lin,LI, Chang-Cheng,JIA, Li-Sheng,LU, Fu-Sui.Synthesis, Structure and Herbicidal Activity of N-(6-Chloropyrid- 3-yl)carbonyl-2-substituted Arylsulfona-mides[J].Chinese Journal of Organic Chemistry,2006,26(2):203-206. |
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| Authors: | JIANG Lin LI Chang-Cheng JIA Li-Sheng LU Fu-Sui |
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| Institution: | College of Chemistry and Materials Science, Shandong Agricultural University, Taian 271018 |
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| Abstract: | Five novel N-(6-chloropyrid-3-yl)carbonyl-2-substituted arylsulfonamides 3a～3e were synthesized through the condensation of 6-chloropyrid-3-yl carboxylic acid (2) with 2-substituted arylsulfonamides (1) and characterized by elemental analyses, 1H NMR and IR spectra. The crystal structure of compound 3a was determined by X-ray diffraction analysis, which belongs to triclinic, space group . The preliminary bioassays showed that 3a～3d are of good plant-inhibiting activities and the activities to dicotyledon are superior to monocotyledon. |
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| Keywords: | arylsulfonamide synthesis crystal structure herbicidal activity |
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