| 微波辐射无溶剂条件下快速合成2,4,6-三芳基吡啶四氟硼酸盐 |
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| 引用本文： | 王勇,赫庆鹏,李满林,许小晶,尹汉东.微波辐射无溶剂条件下快速合成2,4,6-三芳基吡啶四氟硼酸盐[J].有机化学,2008,28(4):718-722. |
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| 作者姓名： | 王勇 赫庆鹏 李满林 许小晶 尹汉东 |
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| 作者单位： | 1. 聊城大学化学化工学院,聊城,252059
2. 西北农林科技大学理学院,杨凌,712100 |
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| 基金项目： | 国家自然科学基金，山东省自然科学基金 |
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| 摘 要： | 在微波辐射无溶剂条件下快速、高产率地合成了2,4,6-三芳基吡啶四氟硼酸盐化合物, 并对其进行核磁共振、红外光谱、元素分析表征. 同时得到了化合物4f的晶体, 对其进行了X单晶射线衍射表征. 结果表明, 该晶体属正交晶系, 空间群Pbca, a＝2.1050(2) nm, b＝1.64360(17) nm, c＝2.9209(3) nm, α＝β＝90.00°, γ＝90.00°, Dc＝1.276 g?cm－3, V＝10.1057(17) nm－3, Z＝16.
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| 关 键 词： | 微波辐射 无溶剂 2 4 6-三芳基吡啶四氟硼酸盐 合成 |
| 收稿时间： | 2007-7-7 |
| 修稿时间： | 2007年7月16日 |
Rapid Synthesis of 2,4,6-Triarylpyridinium Tetrafluoroborates under the Microwave Irradiation and Sovlent-Free Conditions |
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| WANG Yong,HE Qing-Peng,LI Man-Lin,XU Xiao-Jing,YIN Han-Dong.Rapid Synthesis of 2,4,6-Triarylpyridinium Tetrafluoroborates under the Microwave Irradiation and Sovlent-Free Conditions[J].Chinese Journal of Organic Chemistry,2008,28(4):718-722. |
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| Authors: | WANG Yong HE Qing-Peng LI Man-Lin XU Xiao-Jing YIN Han-Dong |
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| Institution: | (College of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252059)(College of Science, Northwest A&F University, Yangling 712100) |
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| Abstract: | 2,4,6-Triarylpyridinium tetrafluoroborates have been rapidly synthesized in good yields under microwave irradiation and sovlent-free conditons, and characterized by NMR, IR spectra and elemental analyses. Meanwhile, the crystals of compound 4f were obtained and determined by X-ray single-crystal diffraction. The crystal of the compound belongs to orthorhombic system with space group Pbca, a＝2.1050(2) nm, b＝1.64360(17) nm, c＝2.9209(3) nm, α＝β＝90.00°, γ＝90.00°, Dc＝1.276 g?cm－3, V＝10.1057(17) nm－3, and Z＝16. |
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| Keywords: | microwave irradiation sovlent-free 2 4 6-triarylpyridinium tetrafluoroborate synthesis |
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